The diastereoisomeric 6,7-dihydroxycycloundecyl iodides (3a), (3b), and (3c) have been synthesized; their conversion into cycloundecanone (12) in the presence of sodium borohydride and traces of cobalt complexes provides the first catalytic model for the coenzyme B12 catalysed dioldehydratase reaction.
P. Müller and J. Rétey, J. Chem. Soc., Chem. Commun., 1983, 1342 DOI: 10.1039/C39830001342
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