Issue 22, 1983

The transformation of arenes into acetyl dienes via nucleophilic addition to arene–Cr(CO)3 complexes and trapping with Mel

Abstract

Anionic cyclohexadienyl–Cr(CO)3 complexes, formed by addition of reactive carbanions to benzene–Cr(CO)3 and naphthalene–Cr(CO)3 complexes, react with Mel by addition and carbonylation to yield disubstituted cyclohexadienes and dihydronaphthalenes, respectively.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1320-1322

The transformation of arenes into acetyl dienes via nucleophilic addition to arene–Cr(CO)3 complexes and trapping with Mel

E. P. Kündig and D. P. Simmons, J. Chem. Soc., Chem. Commun., 1983, 1320 DOI: 10.1039/C39830001320

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