Three doubly bridged FeII-porphyrins are synthesized having a cavity formed on one face by an anthracene-containing bridge and an imidazole ligand strapped across the other face; all three models bind oxygen reversibly at ambient temperature, the oxygenated form of the best system being stable for almost 2 days.
A. R. Battersby, S. A. J. Bartholomew and T. Nitta, J. Chem. Soc., Chem. Commun., 1983, 1291 DOI: 10.1039/C39830001291
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