A mixed-valence CoIICoIII compound is obtained by electrochemical oxidation of a dicobalt(II) cofacial dimeric porphyrin; unexpectedly, this compound reacts instantaneously with oxygen, even in the absence of an axial ligand on the cobalt(II), leading to a µ-superoxo dicobalt complex.
Y. L. Mest, M. L'Her, J. Courtot-Coupez, J. P. Collman, E. R. Evitt and C. S. Bencosme, J. Chem. Soc., Chem. Commun., 1983, 1286 DOI: 10.1039/C39830001286
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