Gorgosterol (1), a C30 marine sterol containing cyclopropane in the side chain has been stereoselectively synthesized utilizing orthoester Claisen rearrangement and intramolecular alkylative cyclopropanation.
T. Terasawa, Y. Hirano, Y. Fujimoto and N. Ikekawa, J. Chem. Soc., Chem. Commun., 1983, 1180 DOI: 10.1039/C39830001180
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