The (+)- and (–)-enantiomers of (C3)-[2H3]cyclotribenzylene (or[2,7,12,-2H3]-10,15-dihydro-5H-tribenzo[a,d,g]cyclononene), whose chirality is due to isotopic substitution, were synthesized from (C3)-cyclotriguaiacylene, and their absolute configuration was established as P-(+) or M-(–).
J. Caneceill and A. Collet, J. Chem. Soc., Chem. Commun., 1983, 1145 DOI: 10.1039/C39830001145
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