Asymmetric synthesis (up to 99%) of β-hydroxy-N,N-dimethylacetamides was achieved starting from aldehydes and an optically active sulphoxide containing synthon, the sense of chiral discrimination depending on the intermediate metal enolate.
R. Annunziata, M. Cinquini, F. Cozzi, F. Montanari and A. Restelli, J. Chem. Soc., Chem. Commun., 1983, 1138 DOI: 10.1039/C39830001138
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