The ions [CH3COH]+˙ and [CH3OCOH]+˙ have been characterised by their collisional activation mass spectra and their heats of formation were measured as 865 ± 20 and 661 ± 5 kJ mol–1respectively; [CH3COH]+˙ is the reacting Configuration for H˙ loss from [CH2![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CHOH]+˙.
J. K. Terlouw, J. Wezenberg, P. C. Burgers and J. L. Holmes, J. Chem. Soc., Chem. Commun., 1983, 1121 DOI: 10.1039/C39830001121
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