The exotoxin, Tabtoxin, from Pseudomonas tabaci(the organism responsible for Wildfire disease of tobacco plants) has been synthesised by a stereospecific route involving, as a key stereochemistry-defining step, the cycloaddition of an acylnitroso compound to a cyclohexadiene.
J. E. Baldwin, P. D. Bailey, G. Gallacher, K. A. Singleton and P. M. Wallace, J. Chem. Soc., Chem. Commun., 1983, 1049 DOI: 10.1039/C39830001049
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