Molybdenum complexes of sterically hindered thiols. The preparation and structure of[Mo(CO)2(SC6H2Pri3)3]–
Abstract
The reaction of [MoCl4(thf)2](thf = tetrahydrofuran) with NaSC6H2Pri3 in thf under CO gives [Mo(CO)2(SC6H2 Pri3)3]–(1); an X-ray crystal structure shows a trigonal bipyramidal structure with axial CO groups.