5-Methyl-4-phenyl-1,5-diazacycla-octan-2-one has been prepared by cyclisation of an acyclic precursor or by transamidation from 4-phenylazetidin-2-one, and converted into natural (–)-homaline and epi-homaline: the approach is applicable to the synthesis of unsymmetrical alkaloids.
L. Crombie, R. C. F. Jones, Ab. R. Mat-Zin and S. Osborne, J. Chem. Soc., Chem. Commun., 1983, 960 DOI: 10.1039/C39830000960
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