Issue 17, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and reactivity of cyclonickelated compounds. Crystal and molecular structure of [Ni(CCF3[double bond, length as m-dash]CCF3CH2C6H4NMe2)(PEt3)(µ-Cl)]2

Christian Arlen,   Michel Pfeffer,   Jean Fischer  and  André Mitschler  

Abstract

o-N,N-Dimethylaminobenzyl-lithium reacted with NiCl2(PR3)2 to give cyclonickelated compounds; hexafluorobut-2-yne was inserted into their Ni–C bonds giving rise to a seven-membered organometallic ring when the phosphine was PMe3, whereas in the case of PEt3 a dimeric compound was obtained.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39830000928
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 928-929

Permissions

Request permissions

Synthesis and reactivity of cyclonickelated compounds. Crystal and molecular structure of [Ni(CCF3[double bond, length as m-dash]CCF3CH2C6H4NMe2)(PEt3)(µ-Cl)]2

C. Arlen, M. Pfeffer, J. Fischer and A. Mitschler, J. Chem. Soc., Chem. Commun., 1983, 928 DOI: 10.1039/C39830000928

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements