A stereoselective synthesis of compound (2), a model of bruceantin (1), is described that employs an efficient approach to the construction of the pentacyclic skeleton via an intramolecular Diels–Alder reaction.
K. Shishido, T. Saitoh, K. Fukumoto and T. Kametani, J. Chem. Soc., Chem. Commun., 1983, 852 DOI: 10.1039/C39830000852
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