Issue 15, 1983

Structural studies on mixed iron–gold clusters with bidentate tertiary phosphine ligands

Abstract

Structural analyses on [Fe(CO)4Au2(dppm)]2(1a)[dppm =(Ph2P)2CH2] and [Fe(CO)4Au2(dppe)]2(1b)[dppe =(Ph2P)2C2H4] have demonstrated that the bite angle of the phosphine ligands exerts a profound influence on the cluster geometry, since (1a) has a rhomboid of gold atoms with µ2-Fe(CO)4 moieties, and (1b) has well separated Au2Fe triangles.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 843-845

Structural studies on mixed iron–gold clusters with bidentate tertiary phosphine ligands

C. E. Briant, K. P. Hall and D. M. P. Mingos, J. Chem. Soc., Chem. Commun., 1983, 843 DOI: 10.1039/C39830000843

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