Issue 15, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Iridium(V) and rhodium (V) intermediates in aromatic metallation; the unusual reactivity of iodobenzene

Manuel Gómez,   David J. Robinson  and  Peter M. Maitlis  

Abstract

[(C5Me5)Ir(Me)2(Me2SO)] reacts with arenes (C6H5X) to give methane and a mixture of m- and p-substituted [(C5Me5)Ir(Me)(C6H4X)(Me2SO)]; the order of reactivity is X = I > NO2 > CF3 > Br > H > OMe > Cl > F > Me; iridium (V) species are proposed as intermediates.

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Article information

DOI
https://doi.org/10.1039/C39830000825
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 825-826

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Iridium(V) and rhodium (V) intermediates in aromatic metallation; the unusual reactivity of iodobenzene

M. Gómez, D. J. Robinson and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1983, 825 DOI: 10.1039/C39830000825

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