In an unusual double-substitution reaction, the diarylphosphine oxide anion reacts with oxiranes to give bis(phosphine oxides) that can have functional groups on the aryl ring and/or the bridging carbons between the PO groups.
R. L. Wife, A. B. van Oort, J. A. van Doorn and P. W. N. M. van Leeuwen, J. Chem. Soc., Chem. Commun., 1983, 804 DOI: 10.1039/C39830000804
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