Issue 15, 1983

Intramolecular competition experiments on sulphide vs. thiocarbonyl oxidation. Evidence for electronic and steric deactivation of thiocarbonyl groups

Abstract

Addition of m-chloroperbenzoic acid (6) to the thiane-derived thioketene (1) or the thioketone (8) leads to selective oxidation of their respective sulphide groups.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 797-798

Intramolecular competition experiments on sulphide vs. thiocarbonyl oxidation. Evidence for electronic and steric deactivation of thiocarbonyl groups

E. Schaumann, B. Lange and K. Reinholdt, J. Chem. Soc., Chem. Commun., 1983, 797 DOI: 10.1039/C39830000797

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