Phenylthiyl radicals add regiospecifically to isoprenoid chrom-3-enes to yield 3-phenylthiochromans which open to o-prenylphenols on electron transfer from metal naphthalenides or a mercury cathode; the two–step process is tolerant of free phenol and carbonyl functions, and trisubstituted double bonds.
S. E. N. Mohamed, P. Thomas and D. A. Whiting, J. Chem. Soc., Chem. Commun., 1983, 738 DOI: 10.1039/C39830000738
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