The radical anion of triborane(7), B3H7·–, has been generated in solution by abstraction of hydrogen from B3H8– and studied by e.s.r. spectroscopy; MNDO–UHF calculations suggest that B3H7·– has a cyclic C2v structure with a single bridging hydrogen.
J. R. M. Giles, V. P. J. Marti and B. P. Roberts, J. Chem. Soc., Chem. Commun., 1983, 696 DOI: 10.1039/C39830000696
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