Issue 12, 1983

Photoinduced reactions of PtCl62– with saturated hydrocarbons and other C–H containing compounds

Abstract

Light irradiation of a solution of PtCl62– and an n-alkane (hexane or heptane) in MeCO2H or CF3CO2H–H2O yields the corresponding π-olefin complex of PtII, the formation of which is assumed to proceed via a σ-alkyl complex of PtIV; the reaction with acetone, which has no β-hydrogen atoms affords a stable σ-acetonyl complex of PtIV and σ-aryl complexes are formed on irradiation of PtCl62– with arenes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 671-672

Photoinduced reactions of PtCl62– with saturated hydrocarbons and other C–H containing compounds

G. B. Shul'pin, G. V. Nizova and A. E. Shilov, J. Chem. Soc., Chem. Commun., 1983, 671 DOI: 10.1039/C39830000671

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