Issue 11, 1983

Stopping a chromium carousel: X-ray crystallographic and variable-temperature 13C n. m. r. studies on dicarbonyl(hexaethylbenzene)-thiocarbonylchromium(0) and related complexes

Abstract

The low temperature 13C n.m.r. spectrum of (C6Et6)Cr(CO)2CS shows the molecule to have Cs symmetry as it does in the solid state; this result provides the first clear evidence of cessation of tripodal rotation in a neutral half-sandwich compound of Cr.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 634-636

Stopping a chromium carousel: X-ray crystallographic and variable-temperature 13C n. m. r. studies on dicarbonyl(hexaethylbenzene)-thiocarbonylchromium(0) and related complexes

M. J. McGlinchey, J. L. Fletcher, B. G. Sayer, P. Bougeard, R. Faggiani, C. J. L. Lock, A. D. Bain, C. Rodger, E. P. Kündig, D. Astruc, J. Hamon, P. Le Maux, S. Top and G. Jaouen, J. Chem. Soc., Chem. Commun., 1983, 634 DOI: 10.1039/C39830000634

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