Basic phosphines, especially tributylphosphine, when added in 1 : 1 ratio to cationic allylpalladium complexes, allow the selective co-dimerisation of 1,3-dienes and acrylic esters to linear, unsaturated esters, presumably owing to the inducement of an η3–η1 shift of the allyl ligands by the phosphines.
P. Grenouillet, D. Neibecker and I. Tkatchenko, J. Chem. Soc., Chem. Commun., 1983, 542 DOI: 10.1039/C39830000542
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