[Se6I+]n·n[AsF6–] has been prepared quantitatively and its crystal structure determined by single crystal X-ray diffracticn; the cation consists of strands of [Se6I+]n, and the hexaselenium rings, of a chair conformation, are joined to two neighbouring hexaselenium rings by two weak [2.736(3)Å] exocyclic 1,4 axial selenium–iodine bonds.
W. A. S. Nandana, J. Passmore and P. S. White, J. Chem. Soc., Chem. Commun., 1983, 526 DOI: 10.1039/C39830000526
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