Issue 8, 1983

Activation of arene carbon–hydrogen bonds. Direct electrophilic aromatic metallation with a rhodium–porphyrin complex

Abstract

Anion exchange of octaethylporphyrinatorhodium(III) chloride with AgClO4 or AgBF4 results in the formation of a highly electrophilic RhIII–porphyrin capable of direct metallation of arenes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 478-479

Activation of arene carbon–hydrogen bonds. Direct electrophilic aromatic metallation with a rhodium–porphyrin complex

Y. Aoyama, T. Yoshida, K. Sakurai and H. Ogoshi, J. Chem. Soc., Chem. Commun., 1983, 478 DOI: 10.1039/C39830000478

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