Issue 8, 1983

Trimethylphosphine hydrides of molybdenum(II), tungsten(VI), and rhenium(VII): X-ray crystal structure of pentakis(trimethylphosphine)dihydridomolybdenum(II)

Abstract

The reduction of bis(tetrahydrofuran)tetrachloromolybdenum by magnesium under hydrogen in the presence of trimethylphosphine produces MoH2(PMe3)5 whose structure has been determined by X-ray diffraction; the hydrides WH6(PMe3)3 and ReH6(NHPh)(PMe3)2 have also been synthesised.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 476-477

Trimethylphosphine hydrides of molybdenum(II), tungsten(VI), and rhenium(VII): X-ray crystal structure of pentakis(trimethylphosphine)dihydridomolybdenum(II)

M. B. Hursthouse, D. Lyons, M. Thornton-Pett and G. Wilkinson, J. Chem. Soc., Chem. Commun., 1983, 476 DOI: 10.1039/C39830000476

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements