Issue 7, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Activation of mono- and di-nuclear polyhydrides of rhenium: protonation, solvation, and oxidation

Joe D. Allison  and  Richard A. Walton  

Abstract

Activation of the rhenium polyhydrides ReH5(PPh3)2L(L = monodentate ligand) and Re2H8(PPh3)4 has been achieved through their protonation (using HBF4), the formation of solvento-complexes, and their oxidation to reactive paramagnetic cations, strategies which have led to a range of novel species, including [ReH(NCMe)3(PPh3)2L]2+, and [Re2H5(PPh3)4(CNBut)2]+ together with their ‘17-electron’ paramagnetic congeners.

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Article information

DOI
https://doi.org/10.1039/C39830000401
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 401-403

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Activation of mono- and di-nuclear polyhydrides of rhenium: protonation, solvation, and oxidation

J. D. Allison and R. A. Walton, J. Chem. Soc., Chem. Commun., 1983, 401 DOI: 10.1039/C39830000401

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