Issue 7, 1983

α-Phenylation of ketones via tin enolates catalysed by a palladium complex

Abstract

The reaction of tributyltin enolates, prepared from tributyltin methoxide and enol acetates in situ, with bromobenzene in the presence of a catalytic amount of PdCl2(o-tolyl3P)2 was found to give α-phenyl ketones in good yields with essentially complete retetion of the acetate regiochemistry.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 344-345

α-Phenylation of ketones via tin enolates catalysed by a palladium complex

M. Kosugi, I. Hagiwara, T. Sumiya and T. Migita, J. Chem. Soc., Chem. Commun., 1983, 344 DOI: 10.1039/C39830000344

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