The reaction of silver nitrate with tetraethylammonium pentacarbonyliodotungstate(0) in the presence of 1,6,6aλ4- trithiapentalenes gives pentacarbonyltungsten(0) complexes of the thioaldehyde and thioketone valence isomers of 1,6,6aλ4-trithiapentalenes; the symmetrically substituted complexes are fluxional.
P. J. Pogorzelec and D. H. Reid, J. Chem. Soc., Chem. Commun., 1983, 289 DOI: 10.1039/C39830000289
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