Issue 6, 1983

The decomposition of trihalogenoacetic acids in dimethyl sulphoxide: a mild route from carbonyl compounds to trihalogenomethylethanol and trihalogenomethyl ketones

Abstract

Solutions of trichloro- and tribromo-acetic acid in dimethyl sulphoxide in the presence of carbonyl compounds react at room temperature to give insoluble products corresponding to addition of H–CX3 across the carbonyl double bond.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 283-284

The decomposition of trihalogenoacetic acids in dimethyl sulphoxide: a mild route from carbonyl compounds to trihalogenomethylethanol and trihalogenomethyl ketones

P. J. Atkins, V. Gold and W. N. Wassef, J. Chem. Soc., Chem. Commun., 1983, 283 DOI: 10.1039/C39830000283

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