The reaction of D-ribose with stabilised ylides can be made to yield solely acyclic products, which may then be cyclised with high stereoselectivity using phenylselenenyl chloride to produce 1-β-substituted 1-deoxyribose derivatives.
P. D. Kane and J. Mann, J. Chem. Soc., Chem. Commun., 1983, 224 DOI: 10.1039/C39830000224
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