Issue 3, 1983

Trichloroacetic acid in dimethyl sulphoxide as a source of trichloromethyl anions: formation of an adduct and substitution product with 1,3,5-trinitrobenzene

Abstract

Solutions of trichloroacetic acid in dimethyl sulphoxide generate trichloromethyl anions which can be trapped by species susceptible to nucleophilic attack, such as 1,3,5-trinitrobenzene; the procedure is preparatively useful.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 140-141

Trichloroacetic acid in dimethyl sulphoxide as a source of trichloromethyl anions: formation of an adduct and substitution product with 1,3,5-trinitrobenzene

P. J. Atkins and V. Gold, J. Chem. Soc., Chem. Commun., 1983, 140 DOI: 10.1039/C39830000140

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