Issue 3, 1983

An unusual 13-vertex closo-carbacobaltaborane; synthesis and molecular structure of [1-Me-4-(Et3P)-µ4,6-or-7-{Co(PEt3)2-µ-(H)2}-1,2,4-C2CoB10H10]

Abstract

Reaction (room temperature, toluene) of closo-1-Me-1,2-C2B10H11 with two equivalents of [Co(PEt3)4] affords the title compound, structurally identified by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 137-139

An unusual 13-vertex closo-carbacobaltaborane; synthesis and molecular structure of [1-Me-4-(Et3P)-µ4,6-or-7-{Co(PEt3)2-µ-(H)2}-1,2,4-C2CoB10H10]

G. K. Barker, M. P. Garcia, M. Green, F. G. A. Stone and A. J. Welch, J. Chem. Soc., Chem. Commun., 1983, 137 DOI: 10.1039/C39830000137

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