The asymmetric allylation of Grignard reagents by allyl phenyl ethers in the presence of [(–)-(S,S)-2,3-bis (diphenylphosphino) butane](II) chloride gives rise to optically active olefins, with fair to high optical yields; asymmetric induction in the synthesis of 3-ethylcyclohex-1-ene exceeds 97%.
G. Consiglio, F. Morandini and O. Piccolo, J. Chem. Soc., Chem. Commun., 1983, 112 DOI: 10.1039/C39830000112
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