Attack at the carbon atom of co-ordinated η2-CS2 in the complex Pt(CS2)(Ph2P[CH2]2PPh2) by Pt (η2-C2H4)(PPh3)2 in acetone causes fragmentation of CS2 and yields the novel sulphido-bridged dinuclear thiocarbonyl complex (Ph2P[CH2]2PPh2)P[graphic omitted](PPh3)CS.
W. M. Hawling, A. Walker and M. A. Woitzik, J. Chem. Soc., Chem. Commun., 1983, 11 DOI: 10.1039/C39830000011
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