The structure of dibenzo-p-dioxin has been studied by the nematic liquid crystal n.m.r. method. This molecule is solution adopts a folder conformation about the axis connecting the two heteroatoms with an angle of folding of 165.6 ± 2°.
G. Fronza and E. Ragg, J. Chem. Soc., Perkin Trans. 2, 1982, 291 DOI: 10.1039/P29820000291
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