Reaction of sterically congested aromatic ketones with the McMurry reagent (4TiCl3,LiAlH4) in tetrahydrofuran yields is not only the olefins (E- and Z-isomers), but also the corresponding ethanes and some other products. We have studied the minor or non-normal products of this reaction.
F. A. Bottino, P. Finocchiaro, E. Libertini, A. Reale and A. Recca, J. Chem. Soc., Perkin Trans. 2, 1982, 77 DOI: 10.1039/P29820000077
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