Issue 0, 1982

Convenient syntheses of 5-substituted 2- hydroxybenzoates and related reactions

Abstract

The enamine aidehydes RC([double bond, length half m-dash]CHNMe2)CHO (R = Et or Ph) were condensed with the bis-enolate CH2[double bond, length half m-dash]C(O)CH[double bond, length half m-dash]C(O)OEt to give the title aromatic compounds. Thus these products are available from the acetals R1CH2CH(OR2)2(R1= R2= Et; R1= Ph, R2= Me) in two steps. The Vilsmeier formylation of several derivatives of butanal was examined.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1982, 665-669

Convenient syntheses of 5-substituted 2- hydroxybenzoates and related reactions

D. H. R. Barton, G. Dressaire, B. J. Willis, A. G. M. Barrett and M. Pfeffer, J. Chem. Soc., Perkin Trans. 1, 1982, 665 DOI: 10.1039/P19820000665

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