Issue 7, 1982

Inelastic neutron scattering studies of the torsional and librational modes of the anilinium halides, C6H5NH3X

Abstract

The low-frequency modes of vibration of the anilinium ion in the salts C6H5NH3X (where X = Cl, Br or I) have been studied by inelastic neutron scattering, infrared and Raman spectroscopies. In addition, spectra of both the N- and C-deuterated analogues, and also of solid toluene, have been measured. Where possible we have identified the torsional modes of the C6H5— and —NH3+ groups. Barriers calculated from the NH3+ torsions have been compared with the energies of activation obtained from nuclear magnetic resonance studies.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1982,78, 1101-1119

Inelastic neutron scattering studies of the torsional and librational modes of the anilinium halides, C6H5NH3X

K. P. Brierley, J. Howard, K. Robson, T. C. Waddington and C. I. Ratcliffe, J. Chem. Soc., Faraday Trans. 2, 1982, 78, 1101 DOI: 10.1039/F29827801101

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements