Issue 6, 1982

Eigenvalues of the topological matrix. Splitting of graphs with symmetrical components and alternant graphs

Abstract

If a topological matrix M is represented by a graph G then unitary transformation of M to the block-diagonal diag {M1, M2, …} is equivalent to splitting G into disconnected sub-graphs G1, G2, … such that graph G1 represents M1, etc. The eigenvalues of M are those of M1, M2, … separately, and such graph-splitting permits the matrices M1, M2… to be set up by inspection. In the present paper algorithms are given for effecting this graph-splitting for (1) systems which may or may not be symmetrical as a whole but which contain fragments having two-fold symmetry, and (2) alternant systems.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1982,78, 911-916

Eigenvalues of the topological matrix. Splitting of graphs with symmetrical components and alternant graphs

B. J. McClelland, J. Chem. Soc., Faraday Trans. 2, 1982, 78, 911 DOI: 10.1039/F29827800911

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