High-resolution infrared analyses of the CH and CD stretching fundamentals of H2CCD2
Abstract
The two CH stretching vibrations ν1 and ν9 and the two CD stretching vibrations ν11 and ν5 of H2CCD2 have been studied at a resolution of ca. 0.05 cm–1. Upper-state vibrational and rotational parameters for all four bands are obtained, and a number of Coriolis- and Fermi-type resonances have been identified and characterised.
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