The detailed theory reported earlier by Tembe, Friedman and Newton is supplemented by calculations of the electronic overlap of the initial and final states for reaction geometries different from those treated earlier. A dynamical theory of the outer-sphere reorganization process provides an explicit model for deviations from the transition-state theory. These results support the earlier calculation of the rate constant.
H. L. Friedman and M. D. Newton, Faraday Discuss. Chem. Soc., 1982, 74, 73 DOI: 10.1039/DC9827400073
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