Issue 24, 1982

Concerning the isomerization of sila-olefins to silylenes. Some thermochemical kinetic arguments

Abstract

Some apparently conflicting results on the mechanistic behaviour of sila-olefins and their precursors may be resolved by taking account of the different conditions of the experiments and these considerations lead to a plausible activation energy for isomerisation of the sila-olefin.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1415-1417

Concerning the isomerization of sila-olefins to silylenes. Some thermochemical kinetic arguments

R. Walsh, J. Chem. Soc., Chem. Commun., 1982, 1415 DOI: 10.1039/C39820001415

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