X-Ray structure determination of the 1 : 1 complex between copper(II) ion and pyridoxylidene-L-histidine reveals a trimeric molecule (with 100–120 waters of crystallization per cell) where each copper is co-ordinated in a plane by phenolic oxygen, imine nitrogen, and carboxylic oxygen of one Schiff base, and the histidine nitrogen of another ligand, with water in the fifth apical, site.
H. M. Dawes and T. N. Waters, J. Chem. Soc., Chem. Commun., 1982, 1390 DOI: 10.1039/C39820001390
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