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Issue 24, 1982

Biosynthesis of α-cyclopiazonic acid: stereochemical aspects of D-ring formation

Abstract

(3R)-Mevalonic acid lactone is incorporated into α-cyclopiazonic acid with retention of the 4-pro-R-hydrogen atom; [1,2-13C2]acetate has been used as a probe to show that the cyclization of β-cyclopiazonic acid into α-cyclopiazonic acid involves a syn addition to the double bond.

Article information


J. Chem. Soc., Chem. Commun., 1982, 1367-1368
Article type
Paper

Biosynthesis of α-cyclopiazonic acid: stereochemical aspects of D-ring formation

A. A. Chalmers, C. P. Gorst-Allman and P. S. Steyn, J. Chem. Soc., Chem. Commun., 1982, 1367 DOI: 10.1039/C39820001367

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