Complexes of type cis-[PtR2(η1-dppm)2], R = Me, o-tolyl, or 1-naphthyl, can be readily made from cis-[PtR2(η2-dppm)] and then used in the systematic synthesis of diplatinum complexes and heterobimetallic complexes with silver, gold, or rhodium, all containing two bridging dppm groups.
P. G. Pringle and B. L. Shaw, J. Chem. Soc., Chem. Commun., 1982, 1313 DOI: 10.1039/C39820001313
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