Issue 21, 1982

Phosphino sulphonates, a type of PIII-anhydride and their isomerisation into phosphinoyl sulphinates: a novel rearrangement in phosphorus–sulphur chemistry

Abstract

The imidazolides (1) react smoothly with RSO3H to afford a novel class of trico-ordinate phosphorus anhydride, the phosphino sulphonates (2); under sutable structure circumstances the compounds (2) undergo a novel type of rearrangement, (2)→(6), which provides the first example of a phosphinoyl sulphinate structure (6).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1260-1261

Phosphino sulphonates, a type of PIII-anhydride and their isomerisation into phosphinoyl sulphinates: a novel rearrangement in phosphorus–sulphur chemistry

W. Dabkowski, J. Michalski and Z. Skrzypczyński, J. Chem. Soc., Chem. Commun., 1982, 1260 DOI: 10.1039/C39820001260

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