Sensitized photolysis of 1-methyl-1-silabicyclo[2.2.2]octatriene (silabarrelene) quantitatively affords the first example of a silasemibullvalene; no evidence for thermally induced Cope rearrangement of the title compound was found.
M. Vuper and T. J. Barton, J. Chem. Soc., Chem. Commun., 1982, 1211 DOI: 10.1039/C39820001211
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