(±)-Paniculide A was synthesised from 2,4,5,6-tetrahydro-6-methoxycarbonyl-6-methyl-3-phenylthio-benzofuran-2-one (3), readily accessible from methyl α= formylpropionate via annelation with 2,5-dihydro-3-phenylthio-4-vinylfuran-2-one (1).
F. Kido, Y. Noda and A. Yoshikoshi, J. Chem. Soc., Chem. Commun., 1982, 1209 DOI: 10.1039/C39820001209
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