The reaction of photogenerated [ReCl(diphos)2](diphos = Ph2P[CH2]2PPh2) with methanol gives decarbonylation under mild conditions and yields [ReCl(CO)(diphos)2] and [ReClH2(diphos)2].
M. G. Bradley and B. R. Hofmann, J. Chem. Soc., Chem. Commun., 1982, 1180 DOI: 10.1039/C39820001180
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