New chiral phosphine ligands containing a chiral functional group remote from the phosphino-groups have been found to be effective in the palladium-catalysed reaction of allyl acetate with the enolate anion of 2-acetylcyclohexanone and give the allylated product in significant enantiomeric enrichment.
T. Hayashi, K. Kanehira, H. Tsuchiya and M. Kumada, J. Chem. Soc., Chem. Commun., 1982, 1162 DOI: 10.1039/C39820001162
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